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Fe60CoxZr10Mo5W2B23-x(x=1,3,5,7,9)块状金属玻璃的非晶形成能力
引用本文:刘冬艳,张海峰,邓胜涛,胡壮麒.Fe60CoxZr10Mo5W2B23-x(x=1,3,5,7,9)块状金属玻璃的非晶形成能力[J].材料与冶金学报,2005,4(2):111-114,119.
作者姓名:刘冬艳  张海峰  邓胜涛  胡壮麒
作者单位:Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences,Shenyang 110016, China;Graduate School of the Chinese Academy of Sciences, Beijing 100039, China,Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences,Shenyang 110016, China
基金项目:国家重点基础研究发展计划(973计划) , 国家自然科学基金 , 钢铁联合研究基金
摘    要:The bulk Fe60CoxZr10Mo5W2B23-x (x= 1, 3, 5, 7, 9) amorphous rods with diameters of1.5 mm were successfully prepared by copper mold casting method with the low purity raw materials.The amorphous and crystalline states, and thermal parameters, such as the glass transition temperature (Tg), the initial crystallization temperature (Tx), the supercooled liquid region (ΔTx = TxTg), the reduced glass transition temperature Trg (Tg/Tm, Tm: the onset temperature of melting of the alloy, and Tg/T1, T1 : the finished temperature of melting of the alloy) were investigated by X-ray diffractometry (XRD) and differential scanning calorimetry (DSC) analysis. Glass forming ability of Fe60CoxZr10Mo5W2B23-x (x=1, 3, 5, 7, 9)bulk metallic glasses has been studied. According to the results, the alloy (x=7) with the highest Trg (Tg/T1 =0. 607, Tg/T1 =0.590) value, has the strongest glass forming ability among these alloys because its composition is near eutectic composition.The wide supercooled liquid region over 72 K indicates the high thermal stability for this alloy system.This bulk metallic glass exhibits quite high strength (Hv 1020). The success of production of the Febased bulk metallic glass with industrial materials is of great significance for the future progress of basic research and practical application.

关 键 词:bulk  metallic  glasses  glass  forming  ability

Glass forming ability of Fe60 Cox Zr10Mo5 W2B23-x (x = 1,3,5,7,9) bulk metallic glasses
LIU Dong-yan,ZHANG Hai-feng,DENG Sheng-tao,HU Zhuang-qi.Glass forming ability of Fe60 Cox Zr10Mo5 W2B23-x (x = 1,3,5,7,9) bulk metallic glasses[J].Journal of Materials and Metallurgy,2005,4(2):111-114,119.
Authors:LIU Dong-yan  ZHANG Hai-feng  DENG Sheng-tao  HU Zhuang-qi
Affiliation:Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences,Shenyang 110016, China;Graduate School of the Chinese Academy of Sciences, Beijing 100039, China;Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences,Shenyang 110016, China
Abstract:The bulk Fe60CoxZr10Mo5W2B23-x (x= 1, 3, 5, 7, 9) amorphous rods with diameters of1.5 mm were successfully prepared by copper mold casting method with the low purity raw materials.The amorphous and crystalline states, and thermal parameters, such as the glass transition temperature (Tg), the initial crystallization temperature (Tx), the supercooled liquid region (ΔTx = TxTg), the reduced glass transition temperature Trg (Tg/Tm, Tm: the onset temperature of melting of the alloy, and Tg/T1, T1 : the finished temperature of melting of the alloy) were investigated by X-ray diffractometry (XRD) and differential scanning calorimetry (DSC) analysis. Glass forming ability of Fe60CoxZr10Mo5W2B23-x (x=1, 3, 5, 7, 9)bulk metallic glasses has been studied. According to the results, the alloy (x=7) with the highest Trg (Tg/T1 =0. 607, Tg/T1 =0.590) value, has the strongest glass forming ability among these alloys because its composition is near eutectic composition.The wide supercooled liquid region over 72 K indicates the high thermal stability for this alloy system.This bulk metallic glass exhibits quite high strength (Hv 1020). The success of production of the Febased bulk metallic glass with industrial materials is of great significance for the future progress of basic research and practical application.
Keywords:bulk metallic glasses  glass forming ability  thermal stability  copper mould casting
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