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复合型改性木质素絮凝剂处理抗生素类化学制药废水的研究
引用本文:刘明华,杨林,詹怀宇.复合型改性木质素絮凝剂处理抗生素类化学制药废水的研究[J].中国造纸学报,2006,21(2):47-50.
作者姓名:刘明华  杨林  詹怀宇
作者单位:1. 福州大学环境与资源学院,福建,福州,350002
2. 福州大学环境与资源学院,福建,福州,350002;福建省南纸股份有限公司,福建,南平,353000
3. 华南理工大学制浆造纸工程国家重点实验室,广东,广州,510640
基金项目:福建省青年科技人才创新基金项目(2002J002),福建省南平市科技局资助项目(项目编号:N2004Z08)
摘    要:利用有机/无机复合型改性木质素絮凝剂MLF,处理抗生素类化学制药废水,并进行了絮凝条件的优选实验。结果表明,当抗生素制药废水的pH值为6.0,絮凝剂的用量为120 mg/L时,废水中CODCr、SS和色度的去除率分别达到61.2%、96.7%和91.6%。不同类型絮凝剂的对比实验结果表明,MLF处理抗生素类化学制药废水的用量少,絮凝性能明显优于聚丙烯酰胺(PAM)、聚合硫酸铁(PFS)、硫酸铝钾(PAS)和硫酸亚铁(FS)等絮凝剂。

关 键 词:木质素  改性  絮凝剂  制药废水
文章编号:1000-6842(2006)02-0047-04
收稿时间:2006-01-19
修稿时间:2006-01-19

Treatment of Antibiotics Pharmaceutical Effluent with a Novel Compound Modified Lignin-Based Flocculant
LJU Ming-hua,YANG Lin,ZHAN Huai-yu.Treatment of Antibiotics Pharmaceutical Effluent with a Novel Compound Modified Lignin-Based Flocculant[J].Transactions of China Pulp and Paper,2006,21(2):47-50.
Authors:LJU Ming-hua  YANG Lin  ZHAN Huai-yu
Abstract:The sulfomethylated lignoamine was prepared with masson pine lignosulphate by Mannich reaction and sulfonation reaction.Then the organic-inorganic compound modified lignin-based flocculant could be obtained by further mixing with sodium aluminate solution.The modified lignin-based flocculant was adopted to treat the antibiotics pharmaceutical effluent.The flocculation conditions were optimized.The removal rates of COD_(Cr),SS and colourity of the effluent could reach 61.2%,96.7% and 91.6% respectively under such conditions as effluent pH value 6.0 and flocculant dosage 120 mg/L etc.Moreover,the comparison tests with various flocculants indicated that the flocculation performance of the modified lignin-based flocculant apparently prevailed over such flocculants as polyacrylamide(PAM),polyferric sulfate(PFS),potassium aluminium sulfate(PAS) and ferrous sulfate(FS) etc.
Keywords:lignin  modification  sulfomethylated lignoamine  flocculant  pharmaceutical effluent  flocculation
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