| 2,2-双(3-苯基-4-羟基苯基)丙烷的合成研究 |
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| 引用本文： | 张志德,牟海燕,陈玉琴. 2,2-双(3-苯基-4-羟基苯基)丙烷的合成研究[J]. 精细与专用化学品, 2011, 19(4): 24-26 |
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| 作者姓名： | 张志德 牟海燕 陈玉琴 |
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| 作者单位： | 山东师范大学化学化工与材料科学学院,山东,济南,250014 |
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| 基金项目： | 山东省科技攻关项目资助 |
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| 摘 要： | 以邻苯基苯酚和丙酮为原料,盐酸为催化剂,巯基丙磺酸为助催化剂,通过缩合反应合成了2,2-双(3-苯基-4羟基苯基)丙烷(双OPP-A),研究了原料配比、催化剂用量、反应温度、反应时间等因素对反应的影响,通过实验确定了合成双OPP-A的最优条件为:n(邻苯基苯酚):n(丙酮):n(盐酸):n(巯基丙磺酸)=8:2:4:1,反应温度为60℃,反应时间24h,双OPP-A收率达到78.5%,经重结晶纯度达99.2%。产物通过红外光谱和核磁共振等进行了确证。
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| 关 键 词： | 2,2-双(3-苯基-4羟基苯基)丙烷 邻苯基苯酚 双OPP-A 合成 |
Studies on synthesis of 2,2-bis (3-phenyl-4-hydroxyphenyl) propane |
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| ZHANG Zhi-de,MU Hai-yan,CHEN Yu-qin. Studies on synthesis of 2,2-bis (3-phenyl-4-hydroxyphenyl) propane[J]. Fine and Specialty Chemicals, 2011, 19(4): 24-26 |
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| Authors: | ZHANG Zhi-de MU Hai-yan CHEN Yu-qin |
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| Affiliation: | (College of chemistry,Chemical Engineering and Materials Science,Shandong Normal University,Jinan 250014,China) |
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| Abstract: | The 2,2-bis（3-phenyl-4-hydroxyphenyl） propane（bisOPP-A） was synthesized from o-phenylphenol and acetone by using hydrochloric acid as catalyst and 3-mercaptopropanesulfonic acid as catalytic promoter. The effect of molar ratio of starting materials,the reaction temperature and time on the reaction were studied. The optimum conditions for the synthesis of bisOPP-A are as follows：n（o-phenylphenol）：n（acetone）：n （hydrochloric acid）：n（3-mercaptopropanesulfonic acid） =8：2：4：1,reaction temperature is 60℃and reaction time is 24h,and the yield of bisOPP-A is 78.5%,the purity of the product after recrystaUization is 99.2%.The product was assigned by IR and ~1HNMR. |
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| Keywords: | 2 2-bis（3-phenyl-4-hydroxyphenyl） propane o-phenylphenol bisOPP-A synthesis |
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