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Surface tension of pure liquid bismuth and its temperature dependence: Theoretical calculations
Authors:Fathi Aqra  Ahmed Ayyad
Affiliation:
  • Department of Chemistry, Faculty of Science and Technology, Hebron University, P.O. Box 40, Hebron, West Bank, Palestine
  • Abstract:A theoretical method for calculating the surface tension of liquid metals as a function of temperature is proposed. A mathematical equation, based on statistical thermodynamics, is applied to calculate the surface tension of pure liquid bismuth, in the temperature range 545-620 K. The calculated surface tension of liquid bismuth was found to be 388 mJ/m2, which is in excellent agreement with the reported experimental values (374-417 mJ/m2). The surface tension of bismuth decreases linearly with temperature, confirming a negative slope.
    Keywords:Surface chemistry   Surface tension   Bismuth   Temperature dependence
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