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Effect of porosity on the absorbed, reemitted and transmitted light by a geopolymer metakaolin base
Authors:J. Ramó  n Gasca-Tirado,J.C. Rubio-Á  valos,M.S. Muñ  iz-VillarrealA. Manzano-Ramí  rez,J.L. Reyes-AraizaS. Sampieri-Bulbarela,Carlos Villaseñ  or-MoraJ.J. Pé  rez-Bueno,L.M. ApatigaVicente Amigó   Borrá  s
Affiliation:
  • a Centro de Investigaciones y de Estudios Avanzados del I.P.N. Unidad Querétaro, Querétaro, Querétaro, C.P. 76230, Mexico
  • b Faculty of Civil Engineering, Universidad Michoacana de San Nicolás de Hidalgo, Morelia, Michoacán, C.P. 58000, Mexico
  • c Postdoctoral position at Centro de Investigaciones y de Estudios Avanzados del I.P.N. Unidad Querétaro, Querétaro, Querétaro, C.P. 76230, Mexico
  • d Universidad de Guanajuato. Campus Celaya-Salvatierra, Celaya, Guanajuato, C.P. 38060, Mexico
  • e Centro de Investigación y Desarrollo Tecnológico en Electroquímica, Parque Tecnológico Querétaro-San Fandila, C.P. 76700, San Fandila, Pedro Escobedo, Querétaro, Mexico
  • f Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, A.P. 1-1010, Querétaro, Mexico
  • g Instituto de Tecnología de Materiales, Universidad Politécnica de Valencia. Camino de Vera, s/n. C.P. 46022, Valencia Spain
  • Abstract:In the present paper, the optical characterization of a geopolymer synthesized at three different temperatures (40, 60 and 90 °C) is described. The results were correlated to the porosity fraction in order to obtain a photoluminescent geopolymer.A two-flux model was employed to relate the fraction of light absorbed, remitted and transmitted by a representative layer of geopolymer. Porosity was measured by nitrogen adsorption and correlated with the optical properties to determine the fraction of UV/Vis light transmitted through the samples. It was found that the geopolymer synthesize temperature and the incident wavelength greatly affect the fraction of light transmitted by the samples.The UV/Vis spectrum was divided into three zones according to the observed behavior. In the first zone, the difference in transmission fraction was significant; in the second zone, this difference decreased and practically vanished at the third one.Considering the highest transmission fraction at 90 °C, a photoluminescent geopolymer with the strongest emitting peak at 469 nm was synthesized.
    Keywords:Geopolymer   Metakaolin   Optical properties   Aluminosilicate   Photoluminescent
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