A new triazole-maleimide resin via azide-alkyne click chemistry: Synthesis and characterization |
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| Authors: | Xiaofei WangLiqiang Wan Farong Huang Lei Du |
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| Affiliation: | Key Laboratory for Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, PR China |
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| Abstract: | Copper-catalyzed Azide-Alkyne Cycloaddition (CuAAC) was used to synthesize a new series of maleimides with triazole ring moieties (triazole-maleimides, TA-MIs). The physical and thermal properties of the obtained TA-MIs were studied. The TA-MIs showed good solubility in non-proton strong polar solvents such as DMF, DMAc and NMP. The polymerization of TA-MIs can be carried out at a temperature ranged from 140 °C to 250 °C. Td5 of the resulted poly(TA-MIs) reached 335-345 °C under nitrogen. |
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| Keywords: | Azide-alkyne click chemistry Triazole-maleimide Polymers Thermal properties |
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