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A true nanocomposite: Single crystalline Au nanoparticles on single crystalline Fe3O4 nanoparticles
Authors:Zhi-Min CuiZhe Chen  Ling-Yan JiangWei-Guo Song  Lei Jiang
Affiliation:
  • a School of Chemistry and Environment, Beihang University, Beijing, 100191, PR China
  • b National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China
  • Abstract:An Au/Fe3O4 nanocomposite catalyst was fabricated through a simple deposition-precipitation method. The Au/Fe3O4 nanocomposite is a true nanocomposite that has single crystalline Au nanoparticles supported on single crystalline Fe3O4 nanoparticles. Lattice fringes from both Au and Fe3O4 single nanoparticles were simultaneously observed by transmission electron microscope (TEM). This nanocomposite catalyst showed much high activity in low temperature CO oxidation reaction. The Au/Fe3O4 nanocomposite catalyst reaches 100% CO conversion at 40 °C. In comparison, Au/commercial Fe3O4 catalyst needs 375 °C to convert CO. This Au/Fe3O4 nanocomposite is an ideal sample to study synergetic effect between the catalyst and the support at nanoscale.
    Keywords:Nanocomposites   Nanocrystalline materials   Crystal structure   CO oxidation   Fe3O4 nanoparticles
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