| 壳聚糖固载的锌卟啉的合成及表征 |
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| 引用本文： | 金黎明,王韶冉,赵小菁,赵轶男,陈会英,范圣第. 壳聚糖固载的锌卟啉的合成及表征[J]. 化学试剂, 2009, 31(7) |
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| 作者姓名： | 金黎明 王韶冉 赵小菁 赵轶男 陈会英 范圣第 |
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| 作者单位： | 大连民族学院,生命科学学院,辽宁,大连,116600 |
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| 基金项目： | 辽宁省教育厅高校科研计划项目，辽宁省教育厅青年基金，大连民族学院博士启动基金 |
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| 摘 要： | 以苯甲醛、丙酸和吡咯为原料合成四苯摹卟啉(TPP),以TPP为原料,合成四苯基锌卟啉,利用紫外-可见光谱、红外光谱和核磁共振波谱3种表征手段,证实了TPP和四苯基锌卟啉的合成.用天然含氮高分子壳聚糖同载锌卟啉,以期提高锌卟啉的稳定性及催化能力,利用红外光谱技术,证实了壳聚糖固载的锌卟啉的合成.其合成为进一步探讨金属卟啉及壳聚精固载的会属卟啉的仿生催化能力奠定了基础.
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| 关 键 词： | 壳聚精 锌卟啉 合成 表征 |
Synthesis and characterization of chitosan-supported zinc porphyrin |
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| JIN Li-ming,WANG Shao-ran,ZHAO Xiao-jing,ZHAO Yi-nan,CHEN Hui-ying,FAN Sheng-di. Synthesis and characterization of chitosan-supported zinc porphyrin[J]. Chemical Reagents, 2009, 31(7) |
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| Authors: | JIN Li-ming WANG Shao-ran ZHAO Xiao-jing ZHAO Yi-nan CHEN Hui-ying FAN Sheng-di |
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| Affiliation: | College of Biological Science;Dalian Nationalities University;Dalian 116600;China |
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| Abstract: | Tetraphenylporphinate(TPP),which was synthesized using benzaldehyde,propionic acid and pyrrole as the starting materials,was characterized by visible ultraviolet(UV-Vis) spectrometry,infrared(IR) spectrometry and nuclear magnetic spectrometric(NMR) techniques.Zinc tetraphenylporphyrin was synthesized and characterized by UV-Vis,IR and NMR techniques,too.Zinc porphyrin supported on nitrogenous natural polymer-chitosan was synthesized in order to improve the stability and catalyst reactivity and was character... |
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| Keywords: | chitosan zinc porphyrin synthesis characterization |
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