CuO-CeOe/AleO3/FeCrAl monolithic catalysts prepared by in situ combustion synthesis method for preferential oxidation of carbon monoxide |
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Authors: | ZENG Shanghong SU Haiquan LIU Yuan WANG Yan WANG Dongfang |
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Affiliation: | [1]College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China [2]School of Chemical Engineering and Technology, Tianfin University, Tianjin 300072, China |
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Abstract: | This work described in situ combustion synthesis method for depositing CuO-CeO2 on the FeCrAl honeycomb supports. The influence of the solution concentration and the role of the additive were studied and analyzed by scanning electron microscopy (SEM), X-ray diffractometer (XRD), and temperature programmed reduction (TPR) techniques. The results showed that 200 g/L of the active solution was the most appropriate concentration for preparing the monolithic catalysts, and the additives of praseodymium and lanthanum improved the adhesion stability of the monolithic catalysts. The addition of Pr did not greatly affect the catalytic performance, but CO could not be totally converted into CO2 after the addition of La into the CuO-CeO2/Al2O3/FeCrAl catalysts. |
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Keywords: | monolith CuO CeO2 FeCrAl combustion hydrogen preferential oxidation rare earths |
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