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CuO-CeOe/AleO3/FeCrAl monolithic catalysts prepared by in situ combustion synthesis method for preferential oxidation of carbon monoxide
Authors:ZENG Shanghong  SU Haiquan  LIU Yuan  WANG Yan  WANG Dongfang
Affiliation:[1]College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China [2]School of Chemical Engineering and Technology, Tianfin University, Tianjin 300072, China
Abstract:This work described in situ combustion synthesis method for depositing CuO-CeO2 on the FeCrAl honeycomb supports. The influence of the solution concentration and the role of the additive were studied and analyzed by scanning electron microscopy (SEM), X-ray diffractometer (XRD), and temperature programmed reduction (TPR) techniques. The results showed that 200 g/L of the active solution was the most appropriate concentration for preparing the monolithic catalysts, and the additives of praseodymium and lanthanum improved the adhesion stability of the monolithic catalysts. The addition of Pr did not greatly affect the catalytic performance, but CO could not be totally converted into CO2 after the addition of La into the CuO-CeO2/Al2O3/FeCrAl catalysts.
Keywords:monolith  CuO  CeO2  FeCrAl  combustion  hydrogen  preferential oxidation  rare earths
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