Transport properties of LaSrNi1 − x
ScxOy solid solutions |
| |
Authors: | V F Savchenko L V Makhnach I I Emel’yanova V V Pan’kov |
| |
Affiliation: | (1) Institute of General and Inorganic Chemistry, Belarussian Academy of Sciences, ul. Surganova 9, Minsk, 220072, Belarus |
| |
Abstract: | The formation of LaSrNiO4-and LaSrScO4-based solid solutions with the general stoichiometry LaSrNi1 ? x ScxO4 (0 < x < 1) has been studied in air at temperatures from 700 to 1300°C. According to x-ray diffraction results, the former solid solutions exist in the composition range 0 < x ≤ 0.2. Their lattice parameters have been determined, and their resistivity and thermoelectric power have been measured as functions of temperature. Oxygen release and absorption measurements at temperatures from 20 to 1000°C and oxygen partial pressures from 2 to 330 Pa suggest that the presence of scandium has a stabilizing effect on the oxygen sublattice of the solid solutions. The possible mechanisms of this effect are discussed. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|