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锡酸钠与邻胺基苯酚对铝阳极的共同抑氢作用
引用本文:宋玉苏,张燕.锡酸钠与邻胺基苯酚对铝阳极的共同抑氢作用[J].电源技术,2005,29(10):655-658.
作者姓名:宋玉苏  张燕
作者单位:海军工程大学,理学院化学与材料系,湖北,武汉,430033;海军工程大学,理学院化学与材料系,湖北,武汉,430033
摘    要:通过恒电流集气、稳态极化曲线和交流阻抗等电化学方法研究了常温及高温下,碱性介质中锡酸钠与邻胺基苯酚对铝阳极的共同抑氢作用。试验结果表明:锡酸钠与邻胺基苯酚对碱性介质中铝阳极的自腐蚀析氢有着很好的抑制作用。温度升高,铝阳极在碱性介质中的自腐蚀加剧,锡酸钠与邻胺基苯酚的抑氢效率提高,且作用平稳。

关 键 词:锡酸钠  邻胺基苯酚  抑氢性能  铝阳极  碱性介质
文章编号:1002-087X(2005)10-0655-04
修稿时间:2005年1月2日

Cooperative effect of inhibiting H2 evolution for stannate and O-aminophenol on Al anode
SONG Yu-su,ZHANG Yan.Cooperative effect of inhibiting H2 evolution for stannate and O-aminophenol on Al anode[J].Chinese Journal of Power Sources,2005,29(10):655-658.
Authors:SONG Yu-su  ZHANG Yan
Abstract:To control H2 evolution of Al anode in alkaline solution and develop the application of anodic materials based aluminum, the cooperative effect of inhibiting H2 evolution for stannate and O-aminophenol on Al anode in 4 mol/L KOH at room temperature and higher temperature was studied by galvanostatic gathering volumes of hydrogen evolution and stable state polarization curves and electrochemical impedance spectrum. The results show that the inhibitive effect of stannate and O-aminophenol for the H2 evolution of Al anode in alkaline is perfect. At higher temperature, hydrogen evolution of Al anode is aggravated in alkaline solution, at the same time, the inhibitive efficiency for stannate and O-aminophenol becomes superer and the inhibitive efficiency keeps stable.
Keywords:stannate  O-aminophenol  inhibiting H2 evolution  Al anode  alkaline solution
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