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铽-N-苯基邻氨基苯甲酸的合成及荧光性质
引用本文:韩冰,温新兰,陈静,吴松容,吴海生,夏竹芬.铽-N-苯基邻氨基苯甲酸的合成及荧光性质[J].化工技术与开发,2006,35(12):26-28.
作者姓名:韩冰  温新兰  陈静  吴松容  吴海生  夏竹芬
作者单位:湛江师范学院生化学院,广东,湛江,524048
基金项目:湛江师范学院校科研和教改项目
摘    要:采用共沉淀法制备了稀土铽的N-苯基邻氨基苯甲酸二元配合物.同时,采用溶胶-凝胶法制备了掺杂稀土铽的N-苯基邻氨基苯甲酸二元配合物的SiO2凝胶玻璃复合发光体,研究了合成的2种配合物的热稳定性及荧光性质.结果表明,在凝胶玻璃中合成的稀土二元配合物,其热稳定性明显提高,而其特征荧光基本保持不变.

关 键 词:铽离子  荧光  溶胶-凝胶法
文章编号:1671-9905(2006)12-0026-03
收稿时间:2006-07-11
修稿时间:2006年7月11日

Synthesis of Rare Earth Complexes with N-Phenylanthranilic Acid and its Fluorescence Property
HAN Bing,WEN Xin-lan,CHEN Jing,WU Song-rong,WU Hai-sheng,XIA Zhu-fen.Synthesis of Rare Earth Complexes with N-Phenylanthranilic Acid and its Fluorescence Property[J].Technology & Development of Chemical Industry,2006,35(12):26-28.
Authors:HAN Bing  WEN Xin-lan  CHEN Jing  WU Song-rong  WU Hai-sheng  XIA Zhu-fen
Affiliation:Department of Chemistry, Zhanjiang Normal College, Zhanjiang 524048, China
Abstract:Binary complex of rare earth(Tb) with N-phenylanthranilic acid was synthesized by homogenous precipitation method.In addition,the complex was synthesized by sol-gel method in the gel glass.The thermal decomposition and fluorescence spectra for the gel phosphors were measured.Compared with solid powder complex sample,the thermal stability of this complex was enhanced in SiO_2 host matrix and the fluorescence spectra remained unchanged.
Keywords:terbium ion  flUOrescence p ropetry  sol-gel method
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