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铟-α,α’-联吡啶-硫氰酸铵-氯化四苯胂体系的络合吸附波研究及应用
引用本文:魏显有. 铟-α,α’-联吡啶-硫氰酸铵-氯化四苯胂体系的络合吸附波研究及应用[J]. 冶金分析, 1992, 12(3): 1-1
作者姓名:魏显有
作者单位:甘肃省地矿局中心实验室 兰州
摘    要:本文研究了铟—α,α'-联吡啶-硫氰酸铵-氯化四苯胂体系新的络合吸附波。确定了测定铟的适宜底液条件。铟的检测下限为0.0002μg/ml,波高与铟浓度在0.0004~1μg/ml之间呈线性关系。探讨了极谱波的性质。本法已成功地应用于化探样中痕量铟的测定。

关 键 词:  α  α′-联吡啶  硫氰酸铵  氯化四苯胂

Studies on the Adsorptive Complex Wave System of Indium-a,a''''-Dipyridyl-Ammonium Rhodanide-Tetraphenylarsinium Chloride and Its Application
Wei Xianyou. Studies on the Adsorptive Complex Wave System of Indium-a,a''''-Dipyridyl-Ammonium Rhodanide-Tetraphenylarsinium Chloride and Its Application[J]. Metallurgical Analysis, 1992, 12(3): 1-1
Authors:Wei Xianyou
Abstract:In a pH2.4 buffer solution of HCl-NHUAc containing 0.03%a, a'-dipyridyl, l%ammo-nium rhodanide, 0.00l%tetraphenylarsinium chloride, a new sensitive adsorptive complex wave of indium has been obtained by single-sweep polarography. The detection limit is 0.2ng/ml. The linear relationship is obtained between peak height and concentration of indium in the range of 0.0004-lug/ml. The wavehas been proved to be a polarographic adsorptive complex wave. The method has been applied to determine the trace indium in geological samples with satisfactory results.
Keywords:Indium   a   a'-Dipyridyl   Ammonium rhodanide   Tetraphenylarsonium chloride.
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