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一种多壁碳纳米管/磷钼酸复合膜修饰电极的制备及其对H2O2的电催化
引用本文:罗宿星,伍远辉,曾启华.一种多壁碳纳米管/磷钼酸复合膜修饰电极的制备及其对H2O2的电催化[J].表面技术,2010,39(3):55-57.
作者姓名:罗宿星  伍远辉  曾启华
作者单位:遵义师范学院,遵义,563002;遵义师范学院,遵义,563002;重庆大学,重庆,400045
基金项目:贵州省教育厅自然科学研究资助项目,遵义市科技局基金 
摘    要:制备了多壁碳纳米管/磷钼酸复合膜修饰电极,用交流阻抗法对该电极进行了表征,用循环伏安法研究了该修饰电极对过氧化氢的电催化特性,并对其稳定性进行了测定。实验结果表明:电极表面已修饰了致密的碳纳米管磷钼酸膜;在过氧化氢浓度为3.0~13.0 mmol/L范围内,催化电流与过氧化氢的浓度呈现良好的线性关系;修饰电极具有良好的稳定性。

关 键 词:磷钼酸  碳纳米管  过氧化氢  修饰电极
修稿时间:2010/6/10 0:00:00

A Modified Electrode Preparation Based on Multi-wall Carbon Nanotubes/phosphomolybdic Acid and its Electro-catalytic Characteristics of Hydrogen Peroxide
LUO Su-xing,WU Yuan-hui and Zeng Qi-hua.A Modified Electrode Preparation Based on Multi-wall Carbon Nanotubes/phosphomolybdic Acid and its Electro-catalytic Characteristics of Hydrogen Peroxide[J].Surface Technology,2010,39(3):55-57.
Authors:LUO Su-xing  WU Yuan-hui and Zeng Qi-hua
Affiliation:LUO Su-xing1,WU Yuan-hui1,2,Zeng Qi-hua1(1.Zunyi Normal College,Zunyi 563002,China,2.Chongqing University,Chongqing 400045,China)
Abstract:GC/MWNTs/PMo12O403-modified electrode was prepared and characterized by the electrochemical impedance spectroscopy measurements.It was found that the electrode was modified by carbon nanotubes/phosphomolybdic acid.The electrochemical characteristics of the modified electrode were studied by using cyclic voltammetry.There was a good linear relationship between the peak currents and the concentrations of H2O2 in the range of 3.0~13.0 mmol/L.The modified electrode had good stability.
Keywords:phosphomolybdic acid  carbon nanotube  hydrogen peroxide  modified electrode  
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