| 液晶离聚物/聚苯胺导电复合材料的研究 |
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| 引用本文： | 张爱玲,汪洋,吕震乾,李三喜,王松.液晶离聚物/聚苯胺导电复合材料的研究[J].电源技术,2010,34(8). |
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| 作者姓名： | 张爱玲 汪洋 吕震乾 李三喜 王松 |
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| 作者单位： | 1. 沈阳工业大学,理学院,辽宁沈阳110178
2. 沈阳工业大学,风能研究所,辽宁沈阳110023 |
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| 基金项目： | 教育部留学基金(2006年)资助项目 |
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| 摘 要： | 采用溶液共混,直接共混稀盐酸掺杂二种方法,制备出液晶离聚物(LCI)与聚苯胺(PAn)导电复合材料。红外光谱结果表明醌环模式振动红移了11 cm-1,峰形变宽,是-SO3-吸电子基团作用;DSC结果表明溶液共混复合材料为均相,且复合材料相容性增强;透射电镜结果表明溶液共混复合材料均匀分散且达到纳米级;交流阻抗结果表明直接共混HCl掺杂复合材料,LCI含量为10%时电导率最大为4.26×10-3 S/cm。
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| 关 键 词： | 液晶离聚物 聚苯胺 复合材料 电导率 |
Properties of liquid crystal ionomer/polyaniline |
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| ZHANG Ai-ling,WANG Yang,LV Zhen-qian,LI San-xi,WANG Song.Properties of liquid crystal ionomer/polyaniline[J].Chinese Journal of Power Sources,2010,34(8). |
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| Authors: | ZHANG Ai-ling WANG Yang LV Zhen-qian LI San-xi WANG Song |
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| Affiliation: | ZHANG Ai-ling1,WANG Yang1,LV Zhen-qian2,LI San-xi1,WANG Song1(1.College of Science,Shenyang University of Technology,Shenyang Liaoning 110178,China,2.Institute of Wind Energy,Shenyang Liaoning 110023,China) |
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| Abstract: | Liquid crystalline ionomer(LCI) and eigenstate polyaniline(PAn) were blended by solution blending,and direct blending doping diluted hydrochloric acid to prepare composite materials.The results of IR show that the buffeting peak of the benzoquinone ring mode doping the polyaniline red shifts 11 centimeters,and the shape of peak becomes wider because of-SO3-.DSC proves that the composite materials by solution blending are homogeneous,and the compatibility of composite materials becomes better;TEM shows that ... |
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| Keywords: | liquid crystalline ionomer polyaniline composite material electrical conductivity |
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