| 镧系酞菁类配合物对Li/SOCl2电池的影响 |
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| 引用本文： | 王东,马志云,赵建社,马素杰. 镧系酞菁类配合物对Li/SOCl2电池的影响[J]. 电池, 2011, 41(1): 39-42 |
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| 作者姓名： | 王东 马志云 赵建社 马素杰 |
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| 作者单位： | 王东,马志云,赵建社,WANG Dong,MA Zhi-yun,ZHAO Jian-she(西北大学化学与材料科学学院,合成与天然功能分子化学教育部重点实验室,陕西,西安,710069);马素杰,MA Su-jie(西安机电信息研究所,陕西,西安,710065) |
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| 基金项目： | 国家自然科学基金，教育部高等学校博士学科点专项科研基金 |
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| 摘 要： | 采用微波合成法制备了13种镧系酞菁类配合物ML<,2>(M=La、Ce、Pr、Sm、Nd、Eu、Gd、Tb、Dy、Ho、Er、Yb和Lu,L=C<,65>H<,24>N<,22>O<,13>),并用红外光谱和元素分析法分析样品的结构.LaL<,2>、ceL<,2.、GdL<,2>及LuL<,2>提高了Li/SOCl<,...
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| 关 键 词： | 锢系金属 锂/亚硫酰氯(Li/SOCl2)电池 酞菁配合物 催化机理 |
Effects of phthalocyanines of lanthanides compounds to Li/SOCl_2 battery |
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| WANG Dong,MA Zhi-yun,ZHAO Jian-she,MA Su-jie. Effects of phthalocyanines of lanthanides compounds to Li/SOCl_2 battery[J]. Battery Bimonthly, 2011, 41(1): 39-42 |
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| Authors: | WANG Dong MA Zhi-yun ZHAO Jian-she MA Su-jie |
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| Affiliation: | WANG Dong1,MA Zhi-yun1,ZHAO Jian-she1,MA Su-jie2(1.Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education,Collegeof Chemistry & Materials Science of Northwest University,Xi'an,Shaanxi 710069,China,2.Xi'an Institute of Electrical and Mechanical Services Information,Shaanxi 710065,China) |
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| Abstract: | 13 kinds of phthalocyanine of lanthanides compounds ML2[M=La,Ce,Pr,Sm,Nd,Eu,Gd,Tb,Dy,Ho,Er,Yb and Lu,L=C65H24N22O13] were synthesized by microwave process.The structures were analyzed by infrared spectrum and element analysis techniques.LaL2,CeL2,GdL2 and LuL2 enhanced the performance of Li/SOCl2 battery,compared with the blank battery,when 40 Ω constant resistance discharged to 2.00 V at 25 ℃,the capacity increased 5.00%,6.50%,8.50%and 6.00%,respectively.The outer electrons were the main factor for the catalytic ability by changing the electron density of the compound. |
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| Keywords: | lanthanide metal lithium/thionyl chloride(Li/SOCl2) battery phthalocyanines catalytic mechanism |
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