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HY沸石-ZrSiO4吸附废水中铅离子的研究
引用本文:卓猛,黄丽立,金珊,于廷云,金申.HY沸石-ZrSiO4吸附废水中铅离子的研究[J].化工科技,2011,19(6):7-11.
作者姓名:卓猛  黄丽立  金珊  于廷云  金申
作者单位:辽宁石油化工大学化学与材料科学学院,辽宁抚顺,113001
基金项目:辽宁省自然科学基金资助项目
摘    要:天然沸石具有离子交换特性,可用于废水中重金属离子的吸附处理.作者用硅酸锆和改性HY沸石按照质量比1:1比例混合成泥状,110℃干燥3h,放入电阻炉中在温度800℃下焙烧6h,然后粉碎过筛,制成HY沸石-ZrSiO4吸附剂颗粒.把这种吸附材料用于废水中pb2+处理.结果表明,吸附处理废水中铅离子的最佳条件是:吸附剂用量3...

关 键 词:改性沸石  硅酸锆  吸附剂  铅离子  废水处理

Study on adsorption for Pb2+ in wastewater with modified zeolite (HY)-zirconium silicate
ZHUO Meng,HUANG Li-li,JIN Shan,YU Ting-yun,JIN Shen.Study on adsorption for Pb2+ in wastewater with modified zeolite (HY)-zirconium silicate[J].Science & Technology In Chemical Industry,2011,19(6):7-11.
Authors:ZHUO Meng  HUANG Li-li  JIN Shan  YU Ting-yun  JIN Shen
Affiliation:(School of Chemistry and Materials Science,Liaoning Shihua University,Fushun 113001,China)
Abstract:A natural zeolite tuff was used to adsorb heavy meatal ions for the wastewater processing,utilizing it's capacity of exchanging with other irons.We mixed zirconium silicate with modified zeolite(HY) into a slurry analogous state at an ratio of 1∶1 by weight.The mixture was dried at 110 ℃ for 3 h,then was cured at 800 ℃ for 6 h in the electric resistance furnace.The mixture was broken into paticles,which were sieved for the specific size.The got absorption material can adsorb Pb2+ in the wastewater through this experiment.The results indicated that,for HY zeolite and zirconium silicate system,the adsorption capacity of Pb2+ reached it's maximum 96.87 μg/g at 30 ℃,pH 5~6,and adsorbent 32 g/L,and adsorption for 1 h.While the efficiency of desorption reach 88.7% at 15 ℃,pH 12 and shaking for 1 h.Such material showed a stronger adsorption of Pb2+ comparing with the single system of natural zeolite.However,it is available at a low cost and can be used repeatedly.
Keywords:Modified zeolite  Zirconium silicate  Adsorbent  Lead ion  Wastewater treatment
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