Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes |
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| Authors: | Alexandr Jegorov Tomáš Trnka František Tureček Vladimír Hanuš |
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| Affiliation: | (1) Research Unit, Galena Co., Brani!["scaron"]("/content/m475t57mx6066728/xlarge353.gif") ovská 31, 37005 !["Ccaron"]("/content/m475t57mx6066728/xlarge268.gif") eské Bud!["ecaron"]("/content/m475t57mx6066728/xlarge283.gif") jovice, Czech Republic;(2) Department of Organic Chemistry, Charles University, 128 40 Prague 2, Czech Republic;(3) Department of Chemistry BG 10, University of Washington, WA98195 Seattle, USA;(4) Institute of Physical Chemistry, Czech Academy of Sciences, 18223 Prague, Czech Republic |
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| Abstract: | Attempts to carry out the hydroformylation of allyldiethylamine homogeneously catalyzed by rhodium complexes led to unexpected formation of N,N,N ,N-tetraethyl-1,4-diaminobutane and 4-(diethylamino)-1-butanole as final products. The role of the catalyst on the product formation and the reaction mechanism are briefly discussed. |
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| Keywords: | Hydroformylation allylamines N,N, N![]("</a) /content/m475t57mx6066728/xxlarge8242.gif" alt=" prime" align=" BASELINE" BORDER=" 0" >, N /content/m475t57mx6066728/xxlarge8242.gif" alt=" prime" align=" BASELINE" BORDER=" 0" >-tetraethyl-1,4-diaminobutane 4-(diethylamino)-1-butanole homogeneous catalysis rhodium complexes |
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