Synthesis and characterization of high-voltage cathode material LiNi0.5Mn1.5O4 by one-step solid-state reaction |
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Authors: | Wang Zhi-xing Fang Hai-sheng Yin Zhou-lan Li Xin-hai Guo Hua-jun and Peng Wen-jie |
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Affiliation: | (1) School of Metallurgical Science and Engineering, Central South University, 410083 Changsha, China |
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Abstract: | LiNi0.5Mn1.5O4 was prepared under various conditions by one-step solid-state reaction in air and its properties were investigated by X-ray
diffractormetry (XRD), scanning electron microscopy (SEM) and electrochemical measurement. XRD patterns show that LiNi0.5Mn1.5O4 synthesized under various conditions has cubic spinel structure. SEM images exhibit that the particle size increases with
increasing calcination temperature and time. Electrochemical test shows that the LiNi0.5Mn1.5O4 calcined at 700 °C for 24 h delivers up to 143 mA · h/g, and the capacity retains 132 mA · h/g after 30 cycles.
Foundation item: Project (76600) supported by Postdoctoral Science Foundation of Central South University |
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Keywords: | lithium ion batteries cathode material LiNi0 5Mn1 5O4 solid-state reaction |
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