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CoFe_2O_4磁性光催化材料的制备及其对四环素废水的降解
引用本文:刘馨琳,朱健,秦莹莹,汪慧. CoFe_2O_4磁性光催化材料的制备及其对四环素废水的降解[J]. 材料科学与工程学报, 2017, 0(6): 892-896,969
作者姓名:刘馨琳  朱健  秦莹莹  汪慧
作者单位:江苏大学能源与动力工程学院,江苏镇江,212013
基金项目:江苏省自然科学基金资助项目,中国博士后科学基金资助项目,江苏大学高级人才基金资助项目
摘    要:通过水热法成功制备了CoFe_2O_4磁性光催化材料,并将合成的CoFe_2O_4磁性材料应用于可见光照射下降解四环素(TC)模拟废水,考察了CoFe_2O_4磁性材料的光催化性能,同时考察了CoFe_2O_4制备过程中不同制备条件对其光催化活性的影响。通过捕获实验考察CoFe_2O_4光催化降解四环素的主要活性自由基;经过3次循环实验发现,采用水热法合成的CoFe_2O_4磁性光催化材料具有较好的稳定性,对四环素模拟废水的降解率达到65.78%。

关 键 词:磁性材料  光催化  CoFe2O4  四环素

Photo-degradation of Tetracycline with Prepared CoFe2O4 Magnetic Photocatalyst
Abstract:Due to the unique characteristic of magnetic separation,magnetic materials have been widely used in the field of photocatalysis.The CoFe2O4 magnetic photocatalytic was successfully synthesized by a simple hydrothermal method.It displays promising photocatalytic activity towards the photo-degrading of tetracycline(TC) in aqueous solution.Meanwhile,the effects of different preparation conditions on the photocatalytic activity of CoFe2O4 were investigated.The as-prepared samples were carefully evaluated by XRD,TEM,XPS,VSM,UV-vis DRS.Furthermore,the mechanism was systematically investigated through active species trapping experiment.After three cycling experiments,the hydrothermal synthesis of CoFe2O4 magnetic photocatalytic materials still has good stability and the photocatalyst degradation rate of TC is 65.78%.
Keywords:magnetic materials  photocatalytic  CoFe2O4  tetracycline
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