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FORMATION OF MANGANESE SILICIDE THIN FILMS BY SOLID PHASE REACTION
引用本文:E. Q. Xie,W. W. Wang,N. Jiang and D. Y. He Department of Physics,Lanzhou University,Lanzhou 730000,China. FORMATION OF MANGANESE SILICIDE THIN FILMS BY SOLID PHASE REACTION[J]. 金属学报(英文版), 2002, 15(2): 221-226
作者姓名:E. Q. Xie  W. W. Wang  N. Jiang and D. Y. He Department of Physics  Lanzhou University  Lanzhou 730000  China
作者单位:E. Q. Xie,W. W. Wang,N. Jiang and D. Y. He Department of Physics,Lanzhou University,Lanzhou 730000,China
基金项目:This work has been supported jointly by the National Natural Science Foundation ofChina (Crant No. 69806005),the Natural Scie
摘    要:1. IntroductionThe transition metal silicides have attraeted much attention because of their potentialapplicatiOIl in very large scale integration (VLSI) de.ice[1]. Near-noble metal silicides canbe used as Schottky al1d ohn1ic col1tacts in silicon-based d…

收稿时间:2001-07-31
修稿时间:2001-10-30

FORMATION OF MANGANESE SILICIDE THIN FILMS BY SOLID PHASE REACTION
E.Q.Xie,W.W.Wang,N.Jiang,D.Y.He. FORMATION OF MANGANESE SILICIDE THIN FILMS BY SOLID PHASE REACTION[J]. Acta Metallurgica Sinica(English Letters), 2002, 15(2): 221-226
Authors:E.Q.Xie  W.W.Wang  N.Jiang  D.Y.He
Affiliation:Department of Physics,Lanzhou University,Lanzhou 730000,China
Abstract:Manganese silicide MnSi2-x thin films have been prepared on n-type silicon substratesthrough solid phase reaction. The heterostructures were analyzed by X-ray diffraction,Rutherford backscattering spectroscopy, Fourier transform infrared transmittance spec-troscopy and the four-point probe technique. The results show that two manganese sili-cides have been formed sequentially via the reaction of thin layer Mn with Si substrateat different irradiation annealing stages, i.e., MnSi at 450℃ and MnSi1.73 at 550℃.MnSi1.73 phase exhibits preferred growth after irradiation with infrared. In situ four-point probe measurements of sheet resistance during infrared irradiation annealingshow that nucleation of MnSi and phase transformation of MnSi to MnSi1. 73 occur at410℃ and 530℃, respectively; the MnSi phase shows metallic behavior, while MnSi1.73exhibits semiconducting behavior. Characteristic phonon bands of MnSi2-x silicides,which can be used for phase identification along with conventional XRD techniques,have been observed by FTIR spectroscopy.
Keywords:manganese suicide   in situ sheet resistance   solid phase reaction   infrared spectra
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