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A study on mineralization behavior of amino-terminated hyperbranched polybenzimidazole membranes
Authors:Xiayun Huang  Hongcui Cao  Zixing Shi  Hongjie Xu  Jianhua Fang  Jie Yin  Qiaoling Pan
Affiliation:1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, People’s Republic of China
2. State Key Laboratory for Diagnosis and Treatment of Infectious Diseases, 1st Affiliated Hospital, College of Medicine, Zhejiang University, 79, Qingchun Road, Hangzhou, 310003, People’s Republic of China
3. State Key Labroatory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, People’s Republic of China
Abstract:Amino-bearing polymers, coated with apatite or similar minerals, have attracted significant attention for their potential in medical applications. In this study, an amino-terminated hyperbranched polybenzimidazole (HBPBI) membrane was used as a substrate for apatite growth. The membrane was soaked in solutions of CaCl2, Na2HPO4 and SBF to yield an apatite coating. The structure and morphology of the layers were characterized by FTIR-ATR, XRD and FESEM. The results indicate that the high densities of amino, imide and imidazole groups on the amino-terminated HBPBI membrane provide active sites for the growth of apatite.
Keywords:
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