| 铜酞菁磺酸苯酯的光谱性质研究 |
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| 引用本文： | 殷焕顺,邓建成,向能军. 铜酞菁磺酸苯酯的光谱性质研究[J]. 染料与染色, 2005, 42(5): 19-20 |
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| 作者姓名： | 殷焕顺 邓建成 向能军 |
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| 作者单位： | 湘潭大学化学学院,湘潭,411105;中山大学化学与化学工程学院,广州,510275 |
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| 摘 要： | 将铜酞菁氯磺化,与苯酚酯化,合成了标题化合物。在不同的溶剂中测试其电子光谱:Q带吸收峰为:664.6nm～672.4nm,强度为0.363～1.477;B带吸收峰336.8nm～348.4nm,强度为:0.181～0.708。产物的荧光光谱随溶剂的极性减弱而强度降低:DMF>THF>CH_2Cl_2>DMSO>丙酮>吡啶>CHCl_3;其波长随溶剂的极性减弱而发生蓝移:DMSO>THF>DMF>丙酮>CH_2Cl_2>吡啶>CHCl_3。
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| 关 键 词： | 铜酞菁 电子光谱 荧光光谱 |
| 文章编号： | 1672-1179(2005)05-0019-2 |
| 修稿时间： | 2005-03-01 |
Synthesis and Spectral Properties of Copper Phthalocyanine Sulfonic Phenyl Ester |
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| YIN Huan-shun,DENG Jian-cheng,XIANG Neng-jun. Synthesis and Spectral Properties of Copper Phthalocyanine Sulfonic Phenyl Ester[J]. Ranliao yu Ranse, 2005, 42(5): 19-20 |
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| Authors: | YIN Huan-shun DENG Jian-cheng XIANG Neng-jun |
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| Affiliation: | IYIN Huan-shunl ~1DENG Jian-cheng ~2XIANG Neng-jun |
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| Abstract: | Copper phthalocyanine sulfonic phenyl ester was synthesized from copper phthalocyanine by chlorosulfonating, then esterifying with phenol. The product was characterized by means of IR, UV-Vis, element analysis and TG. It was found that the derivative has good dissolution in some organic solvents. Besides, the properities of electrochemistry and spectra were determined. |
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| Keywords: | copper phthalocyanine copper phthalocyanine sulfonic phenyl ester electron spectra fluorescence spectra |
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