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Synthesis of Li2Fe0.9Mn0.1SiO4/C composites using glucose as carbon source
Authors:Chun-li Peng  Jia-feng Zhang  Xuan Cao and Bao Zhang
Affiliation:School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China
Abstract:Li2Fe0.9Mn0.1SiO4/C composites were synthesized by using glucose as carbon source. The samples were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and electrochemical measurements. All Li2Fe0.9Mn0.1SiO4/C composites are of the similar crystal structure. With increasing the carbon content in the range of 5%-20% (mass fraction), the diffraction peaks in XRD patterns broaden and the particle sizes and the tap density of samples decrease. The Li2Fe0.9Mn0.1SiO4/C composites with carbon content of 14.12% show excellent the capacity retention remains 92.2% after 30 cycles.
Keywords:lithium ion batteries  cathode  lithium iron orthosilicate  carbon coating
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