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Study on the preparation of green suppressors and their characteristics in coal dust flame propagation inhibition
Affiliation:1. College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, PR China;2. Mine Disaster Prevention and Control-Ministry of State Key Laboratory Breeding Base, Shandong University of Science and Technology, Qingdao 266590, PR China;3. Qingdao Intelligent Control Engineering Center for Production Safety Fire Accident, Qingdao 266590, PR China
Abstract:The properties of a green waste molecular sieve-based powder suppressor in inhibiting the flame propagation of coal dust were studied. Waste molecular sieve (S) was pretreated and selected as the carrier, potassium oxalate (K) and ferric citrate (T) as the active components. The reverse dissolution crystallization method was adopted and S@K/T, S@T/K, S@T-K suppressors with different core–shell structure were prepared by different loading sequences. Their particle size, morphology and thermal pyrolysis behavior were compared. The results showed that the particle distribution of three powders is uniform and the dispersity of them is good. The active components of explosion suppression are evenly loaded on the waste molecular sieve carrier and they have different coating structure. The thermal desorption heat of them is 44.64 J/ g, 66.95 J/g and 92.9 J/g, respectively. Furthermore, the flame propagation characteristics of coal dust were tested by the Hartmann flame propagation device. The results showed that all powders had the effect of inhibiting the flame propagation of coal dust and the inhibition effect is S@T-K, S@T/K and S@K/T from strong to weak. Combined with characterization results, the influence mechanism of the difference in the flame propagation inhibition effect of three suppressants was investigated.
Keywords:Waste molecular sieve  Coal dust deflagration  Flame propagation characteristics  Inhibition mechanism
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