| 吸附溶出伏安法测定水中痕量铅 |
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| 引用本文： | 周连君,张淑芳. 吸附溶出伏安法测定水中痕量铅[J]. 青岛科技大学学报(自然科学版), 1995, 0(2) |
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| 作者姓名： | 周连君 张淑芳 |
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| 作者单位： | 曲阜师范大学 |
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| 摘 要： | 在０．０１ｍｏｌ／ＬＨＡｃ－ＮａＡｃ中，铅－乙酸酸缩氨基硫脲（ＧＡＴＳＣ）配合物产生一非常灵敏的吸附还原峰，峰电位是－０．６３Ｖ（Ｖｓ·ＳＣＥ）。峰高与铅浓度在１．０×１０－８￣３．０×１０－７ｍｏｌ／Ｌ范围内成直线关系，检测限是２．０×１０－９ｍｏｌ／Ｌ，该方法用于测量水中痕量铅，结果满意。
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| 关 键 词： | 电化学分析；铅；吸附溶出伏安法 |
Determination of Trace Amounts of Lead in Water by Adsorptive Stripping Voltammetry |
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| Zhou Lianjun, Zhang Shufang. Determination of Trace Amounts of Lead in Water by Adsorptive Stripping Voltammetry[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 1995, 0(2) |
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| Authors: | Zhou Lianjun Zhang Shufang |
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| Affiliation: | Qufu Normal University |
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| Abstract: | A new methed for determination of trace amounts of lead is described. In 0. 01 mol/LHAc-NaAc solution, lead-glyoxalic acid thiosemicarbazone (GATSC) complex produces a very sensitive reduction peak. The peak potential of the wave is -0. 63V (vs. SCE). The change of tile peakheight for lead concentration is liner in the range of 1. 0×10-8￣3. 00×10-7 mol/L. The detectionlimit is 2×10-9 mol/L. The method has been satisfactorily used for the determination of traceamounts of lead in water. |
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| Keywords: | electrochemical analysis lead stripping voltammctry |
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