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Synthesis of a highly selective bis-rhodamine chemosensor for naked-eye detection of Cu2+ ions and its application in bio-imaging
Affiliation:1. Department of Fine Chemistry and Department of Interdisciplinary Bio IT Materials, Seoul National University of Science and Technology, Seoul, 139-743, Republic of Korea;2. Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea;1. College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, PR China;2. School of Arts and Sciences, Shanxi Agricultural University, Taigu 030801, PR China;1. Department of Dynamical Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450011, China;2. School of Pharmacology, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, China;3. Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Hunan Changde 415000, China
Abstract:A bis-rhodamine based fluorescent chemosensor for naked-eye detection of Cu2+ with enhanced sensitivity as compared to mono-rhodamine derivative has been synthesized, and its selectivity for Cu2+ in the presence of other competitive metal ions (Li+, Na+, K+, Cs+, Mg2+, Ca2+, Sr2+, Cr3+, Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Zn2+, Cd2+, Hg2+, and Pb2+), and application in bio-imaging are demonstrated.
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