|
|||||
|
|
Electrocatalytic oxidation of hydroxylamine by (RuPc)2 graphite modified electrode |
|
| Authors: | Mehrdad Ebadi |
| Affiliation: | Chemistry Department, York University, Toronto, Ont., Canada M3J1P3 |
| Abstract: | Electrocatalytic oxidation of hydroxylamine on dinuclear ruthenium phthalocyanine (RuPc)2 modified electrode is studied using cyclic voltammetry (CV) and rotating disc electrode (RDE) techniques. A two-electron oxidation of hydroxylamine to N2O is observed in the pH range of 9–13. A suitable mechanism is proposed by analyzing the rate equation and the Tafel slope. |
| Keywords: | Ruthenium phthalocyanine Electrocatalysis Surface modified electrode Hydroxylamine |
| 本文献已被 ScienceDirect 等数据库收录！ | |