| 氯代芳烃偶联反应中钯催化剂的研究进展 |
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| 引用本文： | 刘建群,陈新兵,安忠维.氯代芳烃偶联反应中钯催化剂的研究进展[J].工业催化,2005,13(7):39-44. |
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| 作者姓名： | 刘建群 陈新兵 安忠维 |
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| 作者单位： | 西安近代化学研究所光电材料中心,陕西,西安,710065;西安近代化学研究所光电材料中心,陕西,西安,710065;西安近代化学研究所光电材料中心,陕西,西安,710065 |
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| 摘 要： | 在合适的钯催化作用下，可将廉价易得、低活性的氯代芳烃应用于C—C键和C杂键形成的偶联反应。对偶联反应用钯催化剂的研究进行了综述。通过选择合适的配体,钯催化剂可有效地催化带有多种体取代基的氯代芳烃或氯代杂芳烃，发生Suzuki、Negishi、Stille和Heck等多种偶联反应，获得较高的收率和很高的选择性。
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| 关 键 词： | 氯代芳烃 钯催化剂 偶联反应 |
| 文章编号： | 1008-1143(2005)06-0039-06 |
| 修稿时间： | 2004年12月4日 |
Recent advances in palladium catalysts for aryl chlorides coupling reaction |
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| LIU Jian-qun,CHEN Xin-bing,AN Zhong-wei.Recent advances in palladium catalysts for aryl chlorides coupling reaction[J].Industrial Catalysis,2005,13(7):39-44. |
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| Authors: | LIU Jian-qun CHEN Xin-bing AN Zhong-wei |
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| Affiliation: | Photoelectric Materials Centre, Xi'an Research Institute of Modern Chemistry, Xi'an 710065，China |
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| Abstract: | Aryl chlorides, an inexpensive material with lower reactivity than bromo aryl or iodo aryl, can be used in the cross coupling reaction forming carbon-carbon bond and carbon-hetero bond when catalyzed by appropriate palladium catalyst. Recent advances in palladium catalysts for coupling reaction of aryl chlorides were reviewed. Palladium catalysts with suitable ligands can effectively catalyze Suzuki coupling, Negishi reaction, Stille reaction and Heck reaction of aryl chlorides and hetero-aryl chlorides. |
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| Keywords: | aryl chloride palladium catalyst coupling reaction |
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