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Optical properties of thermochromic VO2 thin films on stainless steel: Experimental and theoretical studies
Authors:A Lafort  H KebailiS Goumri-Said  O DeparisR Cloots  J De ConinckM Voué  F MirabellaF Maseri  S Lucas
Affiliation:
  • a Université de Liège, ULg, GreenMAT-LCIS, 3 Allée de la chimie, bat B6a, 4000 Liège, Belgium
  • b Université de Mons, UMONS, Laboratoire de physique des surfaces et interfaces, 20 Place du Parc, 7000 Mons, Belgium
  • c University of Namur (FUNDP), Research Centre in Physics of Matter and Radiation (PMR), 61 Rue de Bruxelles, 5000 Namur, Belgium
  • d Université de Mons, UMONS, Physique des matériaux et optique, 20 Place du Parc, 7000 Mons, Belgium
  • e ArcelorMittal Liège Research, Boulevard de Colonster B57, 4000 Liège, Belgium
  • Abstract:Thermochromic films of VO2 were deposited by DC reactive magnetron sputtering on stainless steel substrate. Complex refractive indexes of VO2 were determined by ellipsometric spectroscopy (0.35-16.5 μm) for different film thicknesses. Optical simulations were performed to model the spectral reflectance of the film/substrate system for a film thickness of 100 nm and 200 nm and to monitor the optical contrast of the thermochromic layers by comparing the spectral reflectance at 25 °C and 100 °C. The good agreement observed between experimental and theoretical spectra demonstrates the adequacy of the model for predicting the optical properties of the samples.
    Keywords:Vanadium oxide  Thermochromic materials  Thin films  Multi-layer optical model  Reflectance spectra  Spectroscopic ellipsometry
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