Phase transitions in adsorbed layers VII: A model for mixed gas adsorption on solid surfaces |
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| Affiliation: | 1. Shanghai Engineering Research Center of Biotransformation of Organic Solid Waste, School of Ecological and Environmental Sciences, East China Normal University, Shanghai 200241, PR China;2. College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, PR China;3. Shanghai Key Lab for Urban Ecological Processes and Eco-Restoration, School of Ecological and Environmental Sciences, East China Normal University, Shanghai 200241, PR China;4. Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, PR China;1. Houston Methodist Research Institute, Houston, TX, USA;2. Department of Nephrology, Second Xiangya Hospital, Central South University, Changsha 410011, China;3. Houston Methodist Hospital, Department of Surgery, Houston, TX, USA;4. CNRS UMR 6290, Institute of Genetics and Development of Rennes, Cell Cycle Group, IFR 140 GFAS, France;5. University of Rennes 1, Faculty of Medicine, Rennes, France;6. Department of Regenerative Medicine, Military Institute of Hygiene and Epidemiology (WIHE), Warsaw, Poland;7. University of Texas, MD Anderson Cancer Center, Department of Genetics, Houston, TX, USA;1. Department of Civil and Environmental Engineering, National University of Singapore, 10 Kent Ridge Crescent, 119260, Singapore;2. NUS Environmental Research Institute, National University of Singapore, 5A Engineering Drive 1, #02-01, 117411, Singapore;1. School of Environment, Tsinghua University, 100084, Beijing, China;2. Tianjin Water Recycling Company Limited, 300381, Tianjin, China |
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| Abstract: | A simple model for the adsorption of two-component gaseous mixtures on crystalline solids is developed. This theory is based on the assumption that the adsorbed layer is neither completely localized nor completely mobile. It is shown that the model predicts various phase transitions involving two-dimensional gas, two-dimensional liquid as well as two-dimensional solid phases. The conditions for the appearance of a solid phase are discussed. |
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