Synthesis of a diacetylene-containing polyisophthalate and its third-order nonlinear optical susceptibility |
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Authors: | Miriam F Beristain Alejandra Ortega Gustavo Gomez-Sosa Faisal Halim Ardie Walser |
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Affiliation: | 1. Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de Mexico, Ensenada, México;2. Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Mexico, México;3. Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Mexico, México;4. Electrical Engineering Department, City College of New York, New York, USA |
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Abstract: | In order to obtain amorphous thin films of a polydiacetylene, a polyisophthalate containing a push–pull diacetylene chromophore was synthesized by the reaction of p-(N,N-diethanolamino)-p’-nitrodiphenylbutadiyne with isophthaloyl chloride in anhydrous 1-methyl-2-pyrrolidone. The polymer was soluble in organic solvents, such as chloroform, tetrahydrofuran, dimethylformamide, etc., and films with good optical quality were obtained by spin coating from its N-methyl-2-pyrrolidone solution. It was characterized by 1H-NMR, IR, DSC, UV–Visible, X-ray, etc. The diacetylene groups underwent polymerization in the film when irradiated with UV light at 120 °C under Ar atmosphere, and it contained free radicals with a radical concentration of 1016 radicals/g. The third-order nonlinear optical susceptibility, χ(3), of the polymer film measured by the Z-scan technique at 1064 nm was not noticeable, but when the film was heated and irradiated with UV light, a χ(3) value of 6.4?×?10?10 esu was obtained due to increase in π-conjugation by the formation of polydiacetylene in the side chain. |
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Keywords: | Aromatic diacetylene Z-scan nonlinear optical material amorphous polydiacetylene film |
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