| 8-苄基-2,8-二氮杂双环[4.3.0]壬烷的合成 |
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| 引用本文： | 常瑜,徐华,王秀兰,黄健.8-苄基-2,8-二氮杂双环[4.3.0]壬烷的合成[J].化工生产与技术,2008,15(5):22-23. |
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| 作者姓名： | 常瑜 徐华 王秀兰 黄健 |
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| 作者单位： | 1. 太原理工大学化学工程与技术学院,030024,太原
2. 运城学院应用化学系,044000 |
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| 摘 要： | 采用氢化铝锂还原8-苄基-7,9-二氧代-2,8-二氮杂双环4.3.0]壬烷（C14H16N2O2），得目标产物8-苄基-2,8-二氮杂双环4.3.0]壬烷（C14H20N2），确定了最佳工艺条件。结果表明，以四氢呋喃作溶剂，n(C14H16N2O2):n(LiAlH4)=1:3.2和反应时间为16 h时，产物收率可达93.73%；产物经元素分析、红外光谱分析确认。
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| 关 键 词： | face=Verdana>8-苄基-2 8-二氮杂双环[4.3.0]壬烷 8-苄基-7 9-二氧代-2 8-二氮杂双环[4.3.0]壬烷 氢化铝锂 合成 |
| 收稿时间： | 2008-6-26 |
| 修稿时间： | |
Synthetic of 8-Benzyl-2,8-diazabicyclo[4.3.0]nonane |
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| Chang Yu,Xu Hua,Wang Xiulan,Huang Jian.Synthetic of 8-Benzyl-2,8-diazabicyclo[4.3.0]nonane[J].Chemical Production and Technology,2008,15(5):22-23. |
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| Authors: | Chang Yu Xu Hua Wang Xiulan Huang Jian |
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| Abstract: | The intermediate 8-benzyl-2,8-diazabicyclo4.3.0]nonane (C14H20N2) was synthesized from 8-benzyl-7,9-dioxo-2,8-diazabicyclo4.3.0]nonane (C14H16N2O2)by the reduction of lithium aluminium hydride. The optimal reaction conditions were found as follows: tetrahydrofuran as the solvent,quantity of n(8-benzyl-2,8-diazabicyclo4.3.0]nonane):n(LiAlH4)= 1:3.2,reaction time 16 h,and yield of product reached 93.73%. The product was analyzed qualitatively by means of elemental analysis and IR. |
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| Keywords: | 8-benzyl-2 8-diazabicyclo[4 3 0]nonane 8-benzyl-7 9-dioxo-2 8-diazabicyclo[4 3 0]nonane lithium aluminium hydride synthesis |
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