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含锰车甩汽油见光后诱导期及辛烷值的变化
引用本文:欧育豹,徐国梁,王洁青,张华芝.含锰车甩汽油见光后诱导期及辛烷值的变化[J].石油炼制与化工,2002(4).
作者姓名:欧育豹  徐国梁  王洁青  张华芝
作者单位:国家石油产品质量监督检验中心,国家石油产品质量监督检验中心,国家石油产品质量监督检验中心,国家石油产品质量监督检验中心 北京 100083,北京 100083,北京 100083,北京 100083
摘    要:对加有甲基环戊二烯三羰基锰抗爆剂的车用汽油见光后诱导期、辛烷值的变化进行了试验考察。试验结果表明:含锰车用汽油见光后锰抗爆剂抗爆作用丧失、诱导期急剧下降,汽油变浑浊并有沉淀生成;避光保存时,其性质在半年内不会有大的变化。对金属锰基有机化合物的抗爆作用机理及见光失效原因进行了初步分析,提出了含锰车用汽油在取样、储存及检验过程中应避光操作。对于汽油见光所引起的质量变化,应当引起有关生产、销售、监督及检验等部门的高度重视,并应加强对含锰汽油在储存、使用中发生的变化进行考察和研究。

关 键 词:车用汽油  抗爆添加剂    诱导期  辛烷值  储存稳定性  光氧化

EXPOSURE EFFECT ON INDUCTION PERIOD AND OCTANE NUMBER OF GASOLINE WITH MANGANESE ANTIKNOCK ADDITIVE
Ou Yubao,Xu Guoliang,Wang Jieqing,Zhang Huazhi.EXPOSURE EFFECT ON INDUCTION PERIOD AND OCTANE NUMBER OF GASOLINE WITH MANGANESE ANTIKNOCK ADDITIVE[J].Petroleum Processing and Petrochemicals,2002(4).
Authors:Ou Yubao  Xu Guoliang  Wang Jieqing  Zhang Huazhi
Abstract:The changes of induction period and octane number of gasoline with manganese antiknock additive after exposure were investigated. The tests showed that after gasoline exposure, the antiknock function of the additive was lost; the induction period of the gasoline dropped sharply; and the gasoline became turbid and some deposit formed. When kept the gasoline in protection from light, its property had no obvious change within 6 months. The antiknock mechanism of the organic compound of manganese and the exposure effect were analyzed. It is suggested that exposure of gasoline should be avoided during sampling, storing, and testing, and the departments of production, supervision and testing should pay attention on the matter.
Keywords:automotive gasoline  antiknock additive  manganese  induction period  octane number  storage stability  photo-oxidation  
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