| 二元胶体晶体及二氧化硅复杂有序介孔膜的制备 |
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| 引用本文： | 黄学光,杨正文,孙丽,周济,谢芹,李勃,李龙土.二元胶体晶体及二氧化硅复杂有序介孔膜的制备[J].稀有金属材料与工程,2009,38(Z2). |
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| 作者姓名： | 黄学光 杨正文 孙丽 周济 谢芹 李勃 李龙土 |
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| 作者单位： | 1. 清华大学,新型陶瓷与精细工艺国家重点实验室,北京,100084
2. 清华大学深圳研究生院新材料研究所,广东,深圳,518055 |
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| 摘 要： | 采用模板辅助电场诱导沉积和加速蒸发诱导共沉积两种方法,用聚苯乙烯微球制备了高度有序的二元胶体晶体结构.通过溶胶凝胶法填充这些模板结构,并经过热处理后获得具有复杂有序多孔结构的二氧化硅薄膜.SEM结果表明,所得薄膜较好地复制了胶体晶体模板的结构,薄膜孔径与微球直径相比有一定程度的收缩.与普通多孔膜相比,这种有序多孔膜具有更复杂的结构以及更高的比表面积,在分离提纯、催化剂及光子带隙材料等领域具有一定的应用前景.
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| 关 键 词： | 溶胶凝胶法 二元胶体晶体 复杂有序 介孔 |
Fabrication of Binary Colloidal Crystals and Complex Ordered Mesoporous Silica Films Via Sol-Gel Technology |
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| Huang Xueguang,Yang Zhengwen,Sun Li,Zhou Ji,Xie Qin,Li Bo,Li Longtu.Fabrication of Binary Colloidal Crystals and Complex Ordered Mesoporous Silica Films Via Sol-Gel Technology[J].Rare Metal Materials and Engineering,2009,38(Z2). |
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| Authors: | Huang Xueguang Yang Zhengwen Sun Li Zhou Ji Xie Qin Li Bo Li Longtu |
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| Affiliation: | Huang Xueguang1,Yang Zhengwen1,Sun Li1,Zhou Ji1,Xie Qin1,Li Bo2,Li Longtu1 (1. State Key Lab of New Ceramics , Fine Processing,Tsinghua University,Beijing 100084,China) (2. Advanced Materials Institute,Shenzhen Graduate School,Shenzhen 518055,China) |
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| Abstract: | Binary colloidal crystals consisted of polystyrene microspheres were fabricated via template-assisted electric field induced assembly and accelerated evaporation induced co-assembly,and the corresponding complex ordered mesoporous films were synthesised by sol-gel technology in combination with heat treatments. SEM investigation revealed that the structure of colloidal crystal templates was completely maintained,and the pore size of the films shrank slightly during the sintering process. Compared to usual p... |
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| Keywords: | sol-gel technology colloidal crystal complex order mesoporous |
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