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环氧基苯基硅油改性环氧树脂绝缘胶的研究
引用本文:金小林,郑芸,段景宽,江平开,王宗光.环氧基苯基硅油改性环氧树脂绝缘胶的研究[J].中国胶粘剂,2008,17(2):21-25.
作者姓名:金小林  郑芸  段景宽  江平开  王宗光
作者单位:上海交通大学化学与化工学院,上海市电气绝缘与热老化实验室,上海,200240
摘    要:采用环氧基苯基硅油(PEPDMS)作为环氧树脂绝缘胶的增韧增柔改性剂。研究了PEPDMS对环氧树脂相容性、机械性能、耐热性和电性能的影响。实验结果表明,PEPDMS与环氧树脂具有良好的相容性,对环氧树脂具有显著的增强增韧的效果,且对环氧树脂的耐热性能和电性能无不良影响。但PEPDMS的加入使环氧树脂的玻璃化转变温度(T_g)略有下降。

关 键 词:环氧树脂  硅油  介电性能  绝缘  热分析
文章编号:1004-2849(2008)02-0021-05
收稿时间:2007-10-30
修稿时间:2007-11-13

Study of insulation adhesive based on epoxy resins modified with PEPDMS
JIN Xiao-lin,ZHENG Yun,DUAN Jing-kuan,JIANG Ping-kai,WANG Zong-guang.Study of insulation adhesive based on epoxy resins modified with PEPDMS[J].China Adhesives,2008,17(2):21-25.
Authors:JIN Xiao-lin  ZHENG Yun  DUAN Jing-kuan  JIANG Ping-kai  WANG Zong-guang
Abstract:With polydimethylsiloxane containing epoxy and phenyl group(PEPDMS)as toughening agent and flexibilizer for epoxy resin insulation adhesive,the influence of PEPDMS on the compatibility,mechanical proper- ties,thermal performances,and dielectric behavior of epoxy resin was studied.The results showed that PEPDMS had compatible with the epoxy resin,and the incorporation of PEPDMS in the epoxy resins could significantly im- prove the toughness and flexible strength.At the same time,it did no impairment to the thermal and dielectric per- formances of the epoxy resin.But the addition of PEPDMS caused a decrease in the glass transition temperature (T_g)of the epoxy resin.
Keywords:epoxy resin  polysiloxane  dielectric performances  insulation  thermoanalysis
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