Facile synthesis of luminescent TiO2 nanorods using an anionic surfactant: Their photosensitization and photocatalytic efficiency

Mixed phase (rutile/anatase) TiO₂ nanorods have been synthesized using an anionic surfactant template. Nanorod synthesis has been achieved using mild reaction conditions and without using any rod-shaped template. The shape and crystallinity of the TiO₂ nanomaterials can be modulated by careful control of the surfactant concentration. The novelty of the present work is that the anatase/rutile mixed phase nanorods were formed without using the well-known layer by layer assembly method or the hydrothermal method. These mixed phase TiO₂ nanorods are highly luminescent, can be easily sensitized by fluorescent dyes, show significant dye adsorption ability and function as efficient photocatalysts.