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Removal of Cu2+ from Water Using Liquid-Liquid Microchannel Extraction
Authors:Hui Liu  Shuang Dai  Jun Li  Rui Ma  Yan Cao  Gang Wang  Sridhar Komarneni  Jianhong Luo
Affiliation:1. Sichuan University, Department of Chemical Engineering, 610065 Chengdu, China;2. Shandong University of Science and Technology, Mine Disaster Prevention and Control-Ministry of State Key Laboratory Breeding Base, 266590 Qingdao, China;3. The Pennsylvania State University, Department of Ecosystem Science and Management and Materials Research Institute, Materials Research Laboratory, University Park, PA 16802 Philadelphia, USA
Abstract:The very good extraction selectivity of Cu2+ from water was demonstrated with a new microchannel equipment, by employing di-(2-ethylhexyl)phosphoric acid (D2EHPA) as an extractant and kerosene as a solvent. The effects of different experimental parameters on the extraction efficiency E, the volumetric mass transfer coefficient KLa, and the entrainment were experimentally investigated. The results showed that the extraction efficiency increased with increasing temperature, extractant concentration, phase ratio (organic/aqueous), and pH. The total flow rate, phase ratio, and pH were found to have a great effect on the mass transfer, whereas the temperature and the extractant concentration showed little effect.
Keywords:Cu2+  Extraction efficiency  Liquid-liquid extraction  Mass transfer  Microchannel
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