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A membraneless microfluidic fuel cell with continuous multistream flow through cotton threads
Authors:Rui Wu  Dingding Ye  Rong Chen  Biao Zhang  Xun Zhu  Hang Guo  Zhongliang Liu
Affiliation:1. Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Ministry of Education, Chongqing, China

Institute of Engineering Thermophysics, Chongqing University, Chongqing, China;2. Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Ministry of Education, Chongqing, China;3. MOE Key Laboratory of Enhanced Heat Transfer and Energy Conservation, and Beijing Key Laboratory of Heat Transfer and Energy Conversion, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, China

Abstract:In typical membraneless microfluidic fuel cells, the anolyte and catholyte are driven by syringe pumps, increasing the overall size of the system and limiting its miniaturization. In this study, a membraneless microfluidic fuel cell with continuous multistream flow through cotton threads was proposed. Cotton threads are simply laid in parallel to form flow channels. Multistream flow through cotton threads is formed without any external pumps. Cell performances under various operation conditions are evaluated. The results show that the middle stream could separate other two streams effectively to prevent the diffusive mixing of anolyte and catholyte. A peak power density of 19.9 mW cm−2 and a limiting current density of 111.2 mA cm−2 are delivered. Moreover, the performance improves with the sodium formate concentration rising up to 2M, while it declines at 4M fuel concentration due to the weakened convection transport and product removal caused by the low flow rate. With increasing the flow rate, the performance is enhanced because of the improved fuel transport at the anode. The good performance as well as the constant-voltage discharging curve indicates that the microfluidic fuel cell with cotton threads as flow channels provides a new direction for miniature power sources.
Keywords:alkaline  cotton threads  laminar flow  microfluidic fuel cells  pump free
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