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Inferring kinetic dissolution of NaCl in aqueous glycol solution using a low-cost apparatus and population balance model |
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| Authors: | Caio Felippe Curitiba Marcellos Camila M Senna Figueiredo Frederico W Tavares Maurício Bezerra de Souza Jr Paulo Laranjeira da Cunha Lage João Francisco Cajaiba da Silva Argimiro R Secchi Amaro G Barreto Jr |
| Affiliation: | 1. Department of Chemical Engineering, Federal University of Rio de Janeiro (COPPE), Rio de Janeiro, Brazil;2. Petróleo Brasileiro S.A., Rio de Janeiro, Brazil;3. Department of Chemical Engineering, Federal University of Rio de Janeiro, Rio de Janeiro, Brazil;4. Chemical Institute, Schistochemistry Pole, Federal University of Rio de Janeiro, Rio de Janeiro, Brazil |
| Abstract: | An experimental methodology for inferring brine dissolution rate in monoethylene glycol (MEG) solutions at different temperatures using a webcam combined with a mathematical model is presented. The measurement system is designed to track the RGB (red, green, and blue) colour variations during the dissolution process. A dynamic model augmented with the population balance equation is applied to describe the dissolution process. Moreover, the dissolution rate is consistently related to the temperature and MEG concentration through the driving force based on the Gibbs energy and chemical affinity. The applied low-cost measurement apparatus proved to be a useful resource for tracking the dissolution dynamics in a wide range of undersaturation. |
| Keywords: | dissolution kinetic model population balance sensor sodium chloride |