Development of Co-Cu-C-Mn Catalysts for the Synthesis of Higher Alcohols |
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Authors: | Thomas Wiesmann Arne Reinsdorf Heiko Lohmann Dorit Wolf |
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Affiliation: | 1. Fraunhofer Institute for Environmental, Safety, and Energy Technology UMSICHT, Osterfelder Straße 3, 46047 Oberhausen, Germany;2. Evonik Resource Efficiency GmbH, Rodenbacher Chaussee 4, 63457 Hanau-Wolfgang, Germany |
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Abstract: | Co-Cu catalysts represent a promising possibility to synthesize higher alcohols. In this study, novel carbon-embedded Co-Cu catalysts have been prepared and were tested in an 8-fold parallel reactor system. Moreover, the influence of Mn as a dopant on the catalytic performance has been studied. It was shown that Mn reduced the selectivity for methane and favored the formation of olefins. In contrast to Cu-free catalysts, Cu-containing catalysts have an improved selectivity for alcohols. |
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Keywords: | Cobalt carbide Copper-cobalt catalysts Higher alcohol synthesis Manganese |
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