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Fabrication of films of hydrogen uranyl phosphate tetrahydrate and their use as solid electrolytes in electrochromic displays
Authors:AT Howe  SH Sheffield  PE Childs  MG Shilton
Affiliation:Department of Inorganic and Structural Chemistry, University of Leeds, Leeds LS29JT, Gt. Britain
Abstract:We have found that the high proton conductivity of hydrogen uranyl phosphate tetrahydrate HUO2PO4·4H2O (HUP) is sufficient to enable an HUP/HxWO3 electrochromic cell to function as fast as a cell with an acidic solution electrolyte. Switching times down to 0.3 s were found. The fabrication procedure to obtain the stable and uniform films of HUP required has been optimized, and dense sintered films up to 6 cm in diameter have been produced.
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