Structural changes in a nickel-copper catalyst during growth of nitrogen-containing carbon nanofibers by ethylene/ammonia decomposition |
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Authors: | O.Yu. Podyacheva Z.R. Ismagilov V.A. Ushakov S.V. Tsybulya V.V. Kriventsov |
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Affiliation: | a Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia b Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia |
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Abstract: | Structural changes in a 65Ni-25Cu-Al2O3 catalyst during the decomposition of a C2H4/NH3 mixture at different stages of nitrogen-containing carbon nanofiber (N-CNF) synthesis were studied by X-ray diffraction (XRD) analysis, X-ray diffraction using anomalous scattering effect and extended X-ray absorption fine structure (EXAFS) spectroscopy. The N-CNF growth over a catalyst particle was supposed to proceed via the formation of an oversaturated solid solution of carbon and nitrogen in a nickel-enriched alloy “NiCuxCyNz”. The latter resulted in an increase of the alloy lattice parameter to abnormally large values а = 3.616-3.706 Å without destruction of its cubic structure. The formation of the “NiCuxCyNz” phase and its presence in the system coincide with the optimum time for the synthesis of N-CNFs with the highest nitrogen concentration and maximum values of specific surface area and total pore volume. |
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