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水溶性聚酯的制备及其性能
引用本文:马清芳,程贞娟,秦伟明,黄志超,钱建华.水溶性聚酯的制备及其性能[J].纺织学报,2007,28(6):20-22.
作者姓名:马清芳  程贞娟  秦伟明  黄志超  钱建华
作者单位:浙江理工大学材料与纺织学院 浙江杭州310018
摘    要:以磺酸盐类物质为改性单体,采用共聚法制得水溶性聚酯(WSP),用FTIR、DSC、X射线衍射等测试分析方法对WSP进行表征;研究WSP中改性单体的添加量对其水溶性能、结晶性能及热性能的影响。研究结果表明:通过傅里叶红外变换光谱分析确定了分子链中SO的存在,由此证明SIPE参加了共聚反应;增加改性单体的用量可有效提高共聚酯的水溶性,但其对共聚酯的结晶不利。

关 键 词:水溶性聚酯  改性单体  结晶性能  SIPE  超细纤维
文章编号:0253-9721(2007)06-0020-04
收稿时间:2006-08-15;
修稿时间:2006-08-152006-10-26

Preparation and characterization of water-soluble polyester
MA Qingfang,CHENG Zhenjuan,QIN Weiming,HUANG Zhichao,QIAN Jianhua.Preparation and characterization of water-soluble polyester[J].Journal of Textile Research,2007,28(6):20-22.
Authors:MA Qingfang  CHENG Zhenjuan  QIN Weiming  HUANG Zhichao  QIAN Jianhua
Affiliation:College of Material & Textile;Zhejiang Sci-Tech University;Hangzhou;Zhejiang 310018 China
Abstract:Water-soluble polyester(WSP) was prepared by adding modifying monomer with sulfonic group through copolymerization.And the WSP was characterized by FTIR、DSC and X-ray.The effects of modifying monomer on WSP′s water-solubility and crystallization and thermal property were studied.And the results show that the existence of SO in the molecular chain is confirmed by FTIR,thus proving that SIPE has participated in the copolymerization;and increasing modifying monomer improves the water-solubility of polyester effectively,but it is disadvantageous to its crystallization.
Keywords:water-soluble polyester  modifying monomer  crystallization capacity  SIPE  super-fine fiber
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