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The Physico-chemical Hydrodynamics of Dyeing
Authors:R. McGregor  R. H. Peters  K. Varol
Abstract:Meetings of the Leeds Junior Section, held in the Department of Colour Chemistry and Dyeing, University of Leeds, on 11 November 1969, Mr K. R. F. Cockett in the chair; and of the Manchester Region, held at the Literary and Philosophical Society, Manchester, on 20 November 1969, Mr H. R. Hadfield in the chair Films of methoxymethylnylon 6.6 have been inserted into a stream of dye-liquor. The rates of dyeing of an acid dye at different points down the film were measured. Under some conditions of dyeing, the rate was shown to be controlled by the diffusion in the liquid phase. Values of the thickness of the diffusional boundary layer were calculated from the flux and shown to agree with theory. Modifications of the dyeing conditions, e.g. by increasing the pH or lowering thedyebath concentration, reduced the diffusion coefficient of the dye in the film, and the rate of dyeing became dependent on diffusion both in the film and in the liquid.
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