| 热处理对电解二氧化锰性能的影响 |
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| 引用本文： | 何英 周曲律 李诚芳. 热处理对电解二氧化锰性能的影响[J]. 电池, 1999, 29(3): 107-109 |
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| 作者姓名： | 何英 周曲律 李诚芳 |
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| 作者单位： | 蒙自师范高等专科学校，复旦大学化学系 |
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| 摘 要： | 经２００℃热处理的电解二氧化锰，通过热分析、Ｘ射线衍射分析、红外光谱分析以及表面ｐＨ值和表面积的测定，说明与未处理的电解二氧化锰相比性质发生了变化。经２００℃热处理的电解二氧化锰失去部分结合水而使其红外吸收峰和Ｘ射线衍射峰位移，晶面间距减小，Ｍｎ－Ｏ键力增强，Ｏ—Ｈ键力减弱，表面ｐＨ值降低，比表面积增大，于是出现放电容量增大、电位下降等现象
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| 关 键 词： | 电解二氧化锰 热处理 锌锰电池 一次电池 |
| 修稿时间： | 1998-07-23 |
Influence of Heat Treatment of EMD on Its Performance |
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| Mengzi Teachers' College,Yunnan He Ying Chemical Department,Fudan University,Shanghai Zhou Qulu ) Li Chengfang. Influence of Heat Treatment of EMD on Its Performance[J]. Battery Bimonthly, 1999, 29(3): 107-109 |
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| Authors: | Mengzi Teachers' College Yunnan He Ying Chemical Department Fudan University Shanghai Zhou Qulu ) Li Chengfang |
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| Affiliation: | Mengzi Teachers' College,Yunnan661100 He Ying Chemical Department,Fudan University,Shanghai200433 Zhou Qulu 1) Li Chengfang |
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| Abstract: | The methods of thermal analysis,XRD,IR,ZIA and pH measuring were employed to distinguish EMD and the heat-treated EMD.The results of heat-treated EMD showed that a part of combined water lost,pH descended,the diffraction peaks of XRD and the absorptive peaks of IR displaced,the face interval distance of crystal reduced,the force of Mn-O bond strengthened,the force of O-H bond weakened.These properties of physical chemistry led to that discharge capacity increased,dicharge curve was smooth and the potential descended. |
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| Keywords: | EMD Heat Treatment Zn-MnO 2 Battery Primary Battery |
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