| “镍”催化酰氯和有机锡试剂交叉偶联反应的研究 |
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| 引用本文： | 吴春 刘宝殿. “镍”催化酰氯和有机锡试剂交叉偶联反应的研究[J]. 精细石油化工, 1994, 0(1): 39-42 |
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| 作者姓名： | 吴春 刘宝殿 |
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| 作者单位： | 黑龙江商学院基础部，东北师范大学化学系 哈尔滨 150076 |
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| 摘 要： | 镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。
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| 关 键 词： | 镍络合物 酰氯 有机锡 交叉偶联 |
STUDIES ON NICKEL-CATALYZED CROSS-COUPLING REACTION OF ACID CHLORIDES WITH ORGANOTINS |
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| Wu Chun. STUDIES ON NICKEL-CATALYZED CROSS-COUPLING REACTION OF ACID CHLORIDES WITH ORGANOTINS[J]. Speciality Petrochemicals, 1994, 0(1): 39-42 |
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| Authors: | Wu Chun |
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| Abstract: | The synthesis of ketones by the cross-coupling reaction of organotin reagents with acid chlorides catalyzed by nickel complex was studied. The reaction is more selective, the products are of high yield, and the technique is simpler. Catalytic activity and reaction conditions of different catalysts, such as charge ration, temperature, time, solvent etc. have been investigated under excess of organotin. The optimum reaction conditions were obtained. |
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| Keywords: | Nickel complex Acjd Cloride Orgzuiotin Cross-Coupling |
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