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臭氧破解污泥效能评价指标选择与应用
引用本文:赵玉鑫,尹军,王剑寒.臭氧破解污泥效能评价指标选择与应用[J].哈尔滨工业大学学报,2009(8):79-83.
作者姓名:赵玉鑫  尹军  王剑寒
作者单位:哈尔滨工业大学市政与环境工程学院;吉林建筑工程学院水污染控制与资源化利用重点实验室
基金项目:吉林省重大科技发展资助项目(2004040521);国家水体污染控制与治理科技重大专项资助项目(2008ZX07207-009)
摘    要:为解决污泥臭氧化过程中评价指标不统一问题,考察溶解性化学需氧量(SCOD)、颗粒性化学需氧量(PCOD)、总有机碳(TOC)和挥发性悬浮固体物质(VSS)在污泥臭氧化过程中的表现及相关性,筛选出合适的评价指标,并以此为基础评价过氧化氢和pH对污泥臭氧氧化的影响.结果表明,臭氧消耗量<207.6±7.2mg/gSS时,可将TOC作为首选指标,如超过此范围,可选用SCOD和PCOD作为评价指标.过氧化氢与臭氧最佳摩尔比为1.2,最佳pH为6.

关 键 词:污泥破解  臭氧化  评价指标  过氧化氢  pH

Selection and application of sludge ozonation indicators
ZHAO Yu-xin,YIN Jun,WANG Jian-han.Selection and application of sludge ozonation indicators[J].Journal of Harbin Institute of Technology,2009(8):79-83.
Authors:ZHAO Yu-xin  YIN Jun  WANG Jian-han
Affiliation:1.School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China;2.Jilin Province Key Laboratory of Water Pollution Control and Resources Reuse,Jilin Architectual and Civil Engineering Institute,Changchun 130021,China)
Abstract:In order to select the proper indicator to evaluate the degree of sludge disintegration by ozone under different conditions,the performance and relativity of soluble chemical oxygen demand (SCOD),particle chemical oxygen demand (PCOD),total organic carbon (TOC) and volatile suspended solid (VSS) in the ozonization of sludge were investigated. Then the effect of hydrogen peroxide (H2O2) and pH on the ozonization of sludge was evaluated. Results indicate that TOC is the prior indicator when the ozone dosage is less than 207.6±7.2 mg/gSS. When the ozone dosage is over the obove range,PCOD and SCOD are suitable indicators. The optimum molar ratio of H2O2 to O3is 1.2 and the optimum pH value is 6.
Keywords:sludge decomposition  ozonation  evaluation indicator  hydrogen peroxide  pH value
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