Loading capacity and emulsification phenomena of HREE extraction by dialkylphosphinic acids with different β,γ,δ-substituents |
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作者姓名: | Junlian Wang Guodong Xu Wen Xu Jianguo Cui Yufu Chen Ziyong Chang |
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作者单位: | 1. School of Civil and Resource Engineering,University of Science and Technology Beijing;2. Key Laboratory of Ministry of Education for Efficient Mining and Safety of Metal Mines;3. State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization,Baotou Research Institute of Rare Earths |
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基金项目: | Project supported by the National Natural Science Foundation of China (51974026,21301104); |
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摘 要: | The relationship between dialkylphosphinic acid structure and their loading capacity for HREEs and emulsification phenomena has rarely been studied.In this paper,we took Lu extraction as an example to study the effect of β,γ,δ-substituents of dialkylphosphinic acids on their loading capacity and anti-emulsification performance for HREEs.To discuss conveniently,the dialkylphosphinic acids were classified into two groups:β-substituent group(P208,INET-1,P218,USTB-1 and P227) and γ,δ-substituent gro...
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