Poly(2-amino-4-thiazoleacetic acid)/multiwalled carbon nanotubes modified glassy carbon electrodes for the electrochemical detection of copper(II)

Poly(2-amino-4-thiazoleacetic acid)/multiwalled carbon nanotubes modified glassy carbon electrodes obtained by electropolymerization of 2-amino-4-thiazoleacetic acid, were used for the voltammetric determination of copper ions. The voltammetric response of copper ions at poly(2-amino-4-thiazoleacetic acid)/multiwalled carbon nanotubes modified glassy carbon electrodes was evaluated by differential pulse stripping voltammetry. The peak currents were linearly dependent on the concentrations of the copper ions in the range from 7.0 × 10⁻⁷ M to 5.0 × 10⁻⁵ M, with a coefficiency of 0.9987. The detection limit is 5.0 × 10⁻¹⁰ M calculated for a signal-to-noise ratio of 3 (S/N = 3). And it could be used for the simultaneous determination of copper and cadmium ions. The proposed method was successfully applied to the determination of copper ions in natural water. The concentration of Cu²⁺ was calculated to be 2.0 × 10⁻⁵ M by standard addition method. The recovery rate was 94%.